A Fast and Sustainable Route to Bassanite Nanocrystals from Gypsum
نویسندگان
چکیده
Calcium sulfate is an important construction material. More than 1600 million square meters of interior surfaces are covered with plasterboards in Europe each year. Plasterboard manufactured by transforming mined or recycled gypsum (CaSO4 × 2 H2O) to bassanite ½H2O) a time- and energy-consuming heating process. A fast sustainable way produce solvent-assisted milling, thereby eliminating the need for energy-intensive dehydration, described. The milling reaction complete after ?200 min. Kinetic studies revealed that crystals transform shear forces during milling. 1H nuclear magnetic resonance (NMR) spectroscopic techniques Fourier-transform infrared spectroscopy (FT-IR) show resulting nanocrystals stabilized surface functionalization auxiliary solvent methanol. Bassanite particles produced over extended times 990 min form long-term stable dispersions without stabilizers no signs precipitation. Addition water leads instant agglomeration, followed phase change gypsum. dispersibility volatile methanol elucidation crystallization mechanism allow also applications hybrid materials.
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ژورنال
عنوان ژورنال: Advanced Functional Materials
سال: 2022
ISSN: ['1616-301X', '1616-3028']
DOI: https://doi.org/10.1002/adfm.202111852